I'd have a ?10 handy.
When going outcall I always have an emergency cash purse containing a few ?1 coins (can be used for parking), ?10 note and a ?20 note, plus 1 credit card. The ?10 and the ?20 can be used as change if need be. I don't make the location of the purse obvious, it's a really boring colour, it's hidden by the paraphenalia in my bag and the fee goes in a different place.
Might be worth having a drawer with a ?10, ?5, ?20 in somewhere that isn't in a direct line to the door.